Monday, June 24, 2019

Chapter 1 - Some basic Concepts Of Chemistry

We know that matter is anything which has mass and occupies space. We want to study about the following 3 aspects related to matter:
(i) The composition of matter
(ii) The structure of matter
(iii) The properties of matter
• Chemistry is that branch of science which deals with the above aspects
• Those 3 aspects can be studied in a better way, if we know the basic constituents of matter
• Atoms and molecules are the basic constituents of matter
• Chemistry is in fact the science of atoms and molecules

• Can we see the atoms and molecules with our naked eyes?
• Can we weigh atoms and molecules?
• Can we perceive atoms and molecules?
• In other words, can we make ourselves aware that (and help others become aware that) such minute entities as atoms and molecules do exist?
• In this chapter, we will try to find the answers to these questions


Nature of matter


• We know that, matter can exist in three physical states:
Solid, Liquid and Gas
• The constituent particles of matter has three properties:
(i) Space available between the particles
(ii) Attraction between the particles
(iii) Ability for movement
• The magnitudes of the above three properties are different in solid, liquid and gas. This can be written down in a tabular form:
• We see a regular pattern in the table. So it is easy to remember
• Because of the different conditions experienced by the ‘particles in the 3 different states’, the ‘3 different states’ themselves exhibit different characteristics
• This can also be written down in a tabular form:
• Here also we see a regular pattern in the table. So it is easy to remember

• We know that, the 3 states of matter are interconvertible. This is shown in the diagram below:

    ♦ On heating, solid usually changes to liquid
    ♦ The liquid, on further heating changes into gaseous state
• The reverse process is also applicable:
    ♦ When a gas is cooled, it changes into a liquid
    ♦ The liquid, on further cooling changes into solid state

Now we will see classification of matter. We will write it in steps:
1. At the macroscopic level, matter exists in two forms:
(i) Mixtures  (ii) Pure substances
• This is shown in the diagram below:

2. Many substances present around us are mixtures. Some examples are:
• Sugar solution
    ♦ This is a mixture of sugar and water
• Ocean water
    ♦ This is a mixture of salt and water
• Air
    ♦ This is a mixture of various gases like oxygen, nitrogen, hydrogen etc.,
• Cement mortar
    ♦ This is a mixture of cement, sand and water
• concrete
    ♦ This is a mixture of cement, broken stone, sand and water
3. Mixtures can be further classified as:
(i) Homogeneous mixtures (ii) Heterogeneous mixtures
■ In a homogeneous mixture, the components are mixed thoroughly and uniformly
4. Suppose that, one part of substance A and two parts of substance B are taken to make a mixture  
• We can take any number of samples we like from that mixture
• If that mixture is homogeneous, then:
• In all samples, substances A and B will be present in the ratio 1:2
5. An example is shown in the fig. below:
This fig. is obtained from wikipedia. The links are given below:
Link 1

Link 2

6. In a heterogeneous mixture, the components are not mixed thoroughly. Consider the fig above
• If we take samples from the left side of the heterogeneous mixture, those samples will contain more green particles
• If we take samples from the right side of the heterogeneous mixture, those samples will contain more violet particles
• Rice containing dirt particles like small stones, is an example of heterogeneous mixture

• Note that, no one deliberately mixes dirt with rice. The dirt comes into contact with the rice by accident. Since there is no deliberate mixing, a 'thorough mixing' does not take place. So the dirt is accumulated in some portions of the rice stock. It is a heterogeneous mixture. After processing and cleaning at a mechanized facility, we get pure rice.
7. Well mixed concrete is an example of homogeneous mixture
8. The components of a mixture (both homogeneous and heterogeneous) can be separated by methods like filtration, crystallization, distillation, using separating funnel, simple hand picking, etc.,
9. Next we consider pure substances. Consider a pure substance. We can take any number of samples we like from that substance
• All samples will contain only one substance
• The question of ‘how well the mixing is done’ does not arise
    ♦ Because there is only one substance. We cannot mix it with itself
• The question of ‘in what ratio the mixing is done’ does not arise
    ♦ Because there is only one substance
    ♦ A ratio will be present only if there are more than one substances 
• The question of ‘what method to use to separate the components’ does not arise
    ♦ Because there is only one substance. There is nothing to separate
10. However, pure substances can be further classified as:
(i) Elements (ii) Compounds
11. In elements, there will be only one type of particles. Some examples:
• A sample of sodium consists of only one pure substance: sodium
• A sample of hydrogen consists of only one pure substance: hydrogen
12. But it is important to remember this:
• In a sample of a pure substance, that substance may exist as an atom, or as a molecule
• This depends on the nature of the substance. Some examples:
• A sample of helium will consists of only one pure substance: helium
    ♦ In that sample we will find only individual helium atoms 
• A sample of oxygen will consists of only one pure substance: oxygen
    ♦ In that sample we will find only individual oxygen molecules
    ♦ We will not find any oxygen atoms
    ♦ We have seen the reason in earlier classes (Details here)
13. Next we consider compounds
• We know that, substances like carbon, oxygen, hydrogen etc., are elements
• The atoms of any element will be different from the atoms of other elements
• For example, atom of carbon will be different from the atom of oxygen
 When atoms of different elements combine together, we get ‘molecules of compounds’
Some example:
• A sample of carbon dioxide will consist of molecules of carbon dioxide
    ♦ Each of those molecules will contain one carbon atom and two oxygen atoms
• A sample of water will consist of molecules water
    ♦ Each of those molecules will contain two hydrogen atoms and one oxygen atom
14. We must note an important difference between the following two:
(i) A sample taken from a mixture
(ii) A sample of a compound
• In the first case, we can separate the constituents using physical methods
• In the second case, we cannot separate the constituents using physical methods
    ♦ We will have to use chemical methods to separate them

In the next section, we will see properties of matter and their measurements. We will also see atomic and molecular masses

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